Soft core fluid in a quenched matrix of soft core particles: A mobile mixture in a model gel

We present a density-functional study of a binary phase-separating mixture of soft core particles immersed in a random matrix of quenched soft core particles of larger size. This is a model for a binary polymer mixture immersed in a crosslinked rigid polymer network. Using the replica `trick' for quenched-annealed mixtures we derive an explicit density functional theory that treats the quenched species on the level of its one-body density distribution. The relation to a set of effective external potentials acting on the annealed components is discussed. We relate matrix-induced condensation in bulk to the behaviour of the mixture around a single large particle. The interfacial properties of the binary mixture at a surface of the quenched matrix display a rich interplay between capillary condensation inside the bulk matrix and wetting phenomena at the matrix surface.Comment: 20 pages, 5 figures. Accepted for Phys. Rev.

A model colloidal fluid with competing interactions: bulk and interfacial properties

Using a simple mean-field density functional theory theory (DFT), we investigate the structure and phase behaviour of a model colloidal fluid composed of particles interacting via a pair potential which has a hard core of diameter $\sigma$, is attractive Yukawa at intermediate separations and repulsive Yukawa at large separations. We analyse the form of the asymptotic decay of the bulk fluid correlation functions, comparing results from our DFT with those from the self consistent Ornstein-Zernike approximation (SCOZA). In both theories we find rich crossover behaviour, whereby the ultimate decay of correlation functions changes from monotonic to long-wavelength damped oscillatory decay on crossing certain lines in the phase diagram, or sometimes from oscillatory to oscillatory with a longer wavelength. For some choices of potential parameters we find, within the DFT, a $\lambda$-line at which the fluid becomes unstable with respect to periodic density fluctuations. SCOZA fails to yield solutions for state points near such a $\lambda$-line. The propensity to clustering of particles, which is reflected by the presence of a long wavelength $\gg \sigma$, slowly decaying oscillatory pair correlation function, and a structure factor that exhibits a very sharp maximum at small but non zero wavenumbers, is enhanced in states near the $\lambda$-line. We present density profiles for the planar liquid-gas interface and for fluids adsorbed at a planar hard wall. The presence of a nearby $\lambda$-transition gives rise to pronounced long-wavelength oscillations in the one-body densities at both types of interface.Comment: 14 pages, 11 figure

An evaluation of Skylab (EREP) remote sensing techniques applied to investigations of crustal structure

The author has identified the following significant results. Film positives (70mm) from all six S190A multispectral photographic camera stations for any one scene can be registered and analyzed in a color additive viewer. Using a multispectral viewer, S190A and B films can be projected directly onto published geologic and topographic maps at scales as large as 1:62,500 and 1:24,000 without significant loss of detail. S190A films and prints permit the detection of faults, fractures, and other linear features not visible in any other space imagery. S192 MSS imagery can be useful for rock-type discrimination studies and delineation of linear patterns and arcuate anomalies. Anomalous color reflectances and arcuate color patterns revealed mineralized zones, copper deposits, vegetation, and volcanic rocks in various locations such as Panamint Range (CA), Greenwater (Death Valley), Lava Mountains (CA), northwestern Arizona, and Coso Hot Springs (CA)

Budget Feasible Mechanisms for Experimental Design

In the classical experimental design setting, an experimenter E has access to a population of $n$ potential experiment subjects $i\in \{1,...,n\}$, each associated with a vector of features $x_i\in R^d$. Conducting an experiment with subject $i$ reveals an unknown value $y_i\in R$ to E. E typically assumes some hypothetical relationship between $x_i$'s and $y_i$'s, e.g., $y_i \approx \beta x_i$, and estimates $\beta$ from experiments, e.g., through linear regression. As a proxy for various practical constraints, E may select only a subset of subjects on which to conduct the experiment. We initiate the study of budgeted mechanisms for experimental design. In this setting, E has a budget $B$. Each subject $i$ declares an associated cost $c_i >0$ to be part of the experiment, and must be paid at least her cost. In particular, the Experimental Design Problem (EDP) is to find a set $S$ of subjects for the experiment that maximizes V(S) = \log\det(I_d+\sum_{i\in S}x_i\T{x_i}) under the constraint $\sum_{i\in S}c_i\leq B$; our objective function corresponds to the information gain in parameter $\beta$ that is learned through linear regression methods, and is related to the so-called $D$-optimality criterion. Further, the subjects are strategic and may lie about their costs. We present a deterministic, polynomial time, budget feasible mechanism scheme, that is approximately truthful and yields a constant factor approximation to EDP. In particular, for any small $\delta > 0$ and $\epsilon > 0$, we can construct a (12.98, $\epsilon$)-approximate mechanism that is $\delta$-truthful and runs in polynomial time in both $n$ and $\log\log\frac{B}{\epsilon\delta}$. We also establish that no truthful, budget-feasible algorithms is possible within a factor 2 approximation, and show how to generalize our approach to a wide class of learning problems, beyond linear regression

In vitro toxin production by fusarium solani f. sp. piperis.

Fusarium solani f. sp. piperis (teleomórfico: Nectria haematococca f. sp. piperis) agente causal da podridão-das-raízes e do secamento-dos-ramos da pimenteira-do-reino (Piper nigrum) produz metabólitos secundários com propriedades tóxicas capazes de induzir descoloração das nervuras em folhas destacadas e murcha em micro-estacas. A produção de metabólitos tóxicos alcançou o pico após 25 dias de incubação, sob iluminação. Variações no pH do filtrado da cultura não aumentaram o efeito tóxico, entretanto, quando o pH foi ajustado antes da esterilização do meio de cultura, uma resposta biológica mais intensa foi observada, atingindo o máximo em pH 6,0. Isolados que produziram pigmentos vermelhos no meio de cultura foram mais eficientes em produzir filtrados biologicamente ativos do que aqueles que produziram filtrados de coloração rósea ou branca sugerindo que estes pigmentos podem estar relacionados com atividade toxigênica. Folhas destacadas de sete cultivares de pimenta-do-reino e Piper betle exibiram sintomas de descoloração das nervuras após imersão em filtrados autoclavado e não autoclavado indicando a natureza termoestável destes metabólitos tóxicos

Phase separation in fluids exposed to spatially periodic external fields

We consider the liquid-vapor type phase transition for fluids confined within spatially periodic external fields. For a fluid in d=3 dimensions, the periodic field induces an additional phase, characterized by large density modulations along the field direction. At the triple point, all three phases (modulated, vapor, and liquid) coexist. At temperatures slightly above the triple point and for low (high) values of the chemical potential, two-phase coexistence between the modulated phase and the vapor (liquid) is observed. We study this phenomenon using computer simulations and mean-field theory for the Ising model. The theory shows that, in order for the modulated phase to arise, the field wavelength must exceed a threshold value. We also find an extremely low tension of the interface between the modulated phase and the vapor/liquid phases. The tension is of the order 10^{-4} kB T per squared lattice spacing, where kB is the Boltzmann constant, and T the temperature. In order to detect such low tensions, a new simulation method is proposed. We also consider the case of d=2 dimensions. The modulated phase then does not survive, leading to a radically different phase diagram.Comment: 11 pages, 14 figure

X-Ray Diffraction and Reflectance Spectroscopy of Murchison Powders (CM2) After Thermal Analysis Under Reducing Conditions to Final Temperatures Between 300 and 1300c

The asteroids Ryugu and Bennu have spectral characteristics in common with CI/CM type carbonaceous chondrites and are target bodies for JAXAs Hayabusa2 and NASAs OSIRIS-Rex missions, respectively. Analog studies, based primarily on the Murchison CM2 chondrite, provide a pathway to separate spectral properties resulting space weathering from those inherent to parent-body, mineralogy, chemistry, and processes. Ryugu shares spectral properties with thermally metamorphosed and partly dehydrated CI/CM chondrites. We have undertaken a multidisciplinary study of the thermal decomposition of Murchison powder samples as an analog to metamorphic process that may have occurred on Ryugu. Bulk analyses include thermal And evolved gas analysis, X-ray diffraction (XRD), and VIS-NIR and Mssbauer spectroscopy; micro- to nanoscale analyses included scanning and transmission electron microscopy and electron probe micro analysisWe report here XRD and VIS-NIR analyses of pre- and post-heated Murchison powders, and in a companion paper report results from multiple electron beam techniques

Light emitting diode (LED) color and broiler growth: effect of supplementing blue/green LED to white LED light on broiler growth, stress, and welfare

Light emitting diode (LED) lighting provides an affordable lighting option for use in commercial poultry production. However, more information is needed to understand the effects of LED color on broiler welfare and growth. Five consecutive flocks (1 in summer, 1 in fall, 2 in winter, and 1 in spring) of straight run Ross 708 × Ross 708 broilers were reared in commercial type barns for 45 D. For white only (WO) treatment, birds were reared under white LED only (Agrishift MLB). For white supplemented (WS) treatment, birds were reared under white LED (Agrishift MLB) in the center aisle, with supplemental blue/green LED lighting (Agrishift MLBg) above the feed and water lines on either side of the barn. Each barn housed 26,200 chicks, and there were 2 barns in each treatment (n = 52,400/treatment). Treatments were rotated among barns between each flock. On day 45, blood samples were collected from 20 birds/barn (n = 40/treatment) to assess the plasma corticosterone (CORT) level and heterophil/lymphocyte ratio. On day 45, 100 birds/barn (n = 200/treatment) were weighed individually and assigned scores for hock burn and foot pad dermatitis. All measures were affected by trial (P \u3c 0.001). Plasma CORT and body weight were affected by the treatment × trial interaction (P ≤ 0.001). Overall, birds in the WS treatment had higher day 45 live body weight (P \u3c 0.001) and lower hock burn scores (P = 0.032) than birds in the WO treatment. Birds in the WS treatment had higher day 45 body weight overall (P \u3c 0.001) and in trials 1, 3, and 5, although the overall body weight was lower in trials 1, 3, and 5 than in trials 2 and 4. Supplemental blue/green LED improved hock burn scores and increased overall day 45 body weight. However, trial differences suggest that more data are needed to determine whether supplementing blue/green LED to white LED improves body weight gain in mixed sex broiler chickens

Comparison of an intermittent, short-dawn/dusk photoperiod with an increasing, long-dawn/dusk photoperiod on broiler growth, stress, and welfare

Photoperiod has been shown to significantly affect broiler performance. However, the effects of the traditional 1-min dimming period on broiler growth and welfare are unclear. In this study, 4 consecutive trials were conducted to compare the effects of an intermittent, short-dawn/dusk photoperiod (ISD) to an increasing, long-dawn/dusk photoperiod (ILD) on broiler growth, stress, and welfare. Straight run day-of-hatch Ross 708 × Ross 708 broilers were placed in 1 of 4 commercial broiler barns (2 b of 26,200 birds each per treatment) and grown to 45 D of age. The photoperiod in the ISD treatment consisted of 24L:0D day 0 to 6, 16L:8D day 7 to 13, 12L:4D:2L:6D day 14 to 20, 12L:4D:3L:5D day 21 to 27, 12L:4D:4L:4D day 28 to 41, and 13L:3D:5L:3D day 42 to 45, with a 1-min transition between light and dark periods. The photoperiod in the ILD treatment consisted of 23L:1D day 0 to 7, 16L:8D day 8 to 21, 18L:6D day 22 to 32, and 20L:4D day 33 to 45, with a 1-min light/dark transition period day 0 to 7 and a 30-min transition period day 8 to 45. Treatments were rotated among the barns between trials. On day 45, blood samples were collected from 20 birds/barn (n = 40/treatment) to assess plasma corticosterone (CORT) and heterophil/lymphocyte (H/L) ratio. One hundred birds per barn (n = 200/treatment) were weighed individually and assigned scores for hock burn, foot pad dermatitis, and feather condition on day 45. Trial differences were observed for all measures (P ≤ 0.001). Birds in the ISD treatment were heavier on day 45 (P \u3c 0.001) and had lower hock burn (P = 0.044) and foot pad dermatitis (P \u3c 0.001) scores. Birds in the ILD treatment had lower plasma CORT (P \u3c 0.001) and H/L ratio (P \u3c 0.001). No treatment differences were observed for feather condition (P \u3e 0.05). Overall, birds reared under the intermittent, short-dawn/dusk photoperiod had higher day 45 live body weights and lower hock burn and foot pad dermatitis scores, whereas those reared under the increasing, long-dawn/dusk photoperiod had reduced measures of short-term and long-term stress